| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5228511 | Tetrahedron | 2008 | 10 Pages |
Abstract
The preparation and reactivity of novel (R1O)(R2O)P(BH3)H [R1, R2=Et, TIPS] synthons is investigated. The direct alkylation of these compounds with lithium hexamethyldisilazide (LiHMDS) and various electrophiles, provided new series of phosphonite-borane complexes, which can be converted into H-phosphinates and boranophosphonates.
Graphical abstractThe preparation and reactivity of novel (R1O)(R2O)P(BH3)H [R1, R2=Et, TIPS] synthons is investigated. The direct alkylation of these compounds with lithium hexamethyldisilazide (LiHMDS) and various electrophiles, provided new series of phosphonite-borane complexes, which can be converted into H-phosphinates and boranophosphonates.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yamina Belabassi, Monika I. Antczak, Jennifer Tellez, Jean-Luc Montchamp,