| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5228539 | Tetrahedron | 2008 | 64 Pages |
Abstract
This review is intended to update the impressive amount of developments in the synthesis of cyclic compounds from the Baylis-Hillman chemistry covering the literature from 2003 to 2007. The several reaction strategies leading to these cyclic frameworks discussed in the article are delineated in the figure.
Keywords
DMFDCERCMDMETHFPCCHMDSDMAPDBUTMSOTftrimethylsilyl trifluoromethanesulfonateTBAFTFANCSHMPRDSHFIPTOLNBSPPANMOTFEBOCtrifluoroethanoltBHPtrimethylsilylDPPPCycloAIBNTFAACyclopentadienylPMBEWGN-bromosuccinimideDIEABINAPDDQMVKHMTADIBAL-HDMADBF3·Et2Om-CPBAN-chlorosuccinimidetert-butoxycarbonylmethoxymethyl9-borabicyclo[3.3.1]nonaneCeric(IV) ammonium nitratePMDETATBDPSm-Chloroperoxybenzoic acidTfOHIBXTPAPTHBPBis(trimethylsilyl)amideTMStetrapropylammonium perruthenatep-methoxybenzoyldiastereomeric ratiotriisopropylsilylTsOH2,3-dichloro-5,6-dicyanobenzoquinone1,2-dichloroethane1,2-Dimethoxyethane1,3-bis(diphenylphosphino)propaneDMSOAqueousarylSESTrifluoroacetic anhydrideBoron trifluoride etherateethylAcetylTrifluoroacetic acidp-Toluenesulfonic acidPolyphosphoric acido-Iodoxybenzoic acidBenzylbutyldiastereomeric excessEnantiomeric excessTetrahydrofuranLDAtert-butyldiphenylsilyltert-butyldimethylsilylCyclic compoundsTris(trimethylsilyl)silaneToluenet-BuNucleophilic substitutionRing-closing metathesisRoom temperaturediisopropylethylamineDimethyl acetylenedicarboxylatedimethylformamideDiisobutylaluminum hydrideDimethylsulfoxideMolecular sievesUltrasoundphenylLithium diisopropylamideMoMmicrowaveMethylMethyl vinyl ketonemesylMontmorilloniteCANNucleophileTIPSHeterocyclesHexhexafluoro-2-propanolHexamethylenetetraminehexylBaylis–Hillman reactionPropylpolyethylene glycolPEGPentPentylCatalystpyridinium chlorochromateRate-determining StepCat.electron-withdrawing group
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Vijay Singh, Sanjay Batra,