| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5228747 | Tetrahedron | 2008 | 7 Pages |
Abstract
A Stille coupling reaction of organostannanes with organic halides has been developed in the presence of a catalytic amount of MCM-41-supported bidentate phosphine palladium(0) complex (0.5 mol %) in DMF/H2O (9:1) under air atmosphere in high yields. This polymeric palladium catalyst exhibits higher activity than Pd(PPh3)4 and can be reused at least 10 times without any decrease in activity.
Graphical abstractThe MCM-41-supported bidentate phosphine palladium(0) complex is a highly efficient catalyst for Stille coupling reactions and can be reused 10 times without any decrease in activity.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hong Zhao, Yue Wang, Junchao Sha, Shouri Sheng, Mingzhong Cai,