| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5228884 | Tetrahedron | 2008 | 6 Pages |
Abstract
Phosphites are less reactive than cyanide and carbenes, but silyl migration (Brook rearrangement) strongly favors the umpolung step both kinetically (TS is shown) and thermodynamically.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Maria Schumacher, Bernd Goldfuss,