| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5228947 | Tetrahedron | 2008 | 5 Pages |
Abstract
The effect of N-heterocyclic carbene (NHC) ligands on the catalytic activity of in situ generated palladium complexes in the model cross-coupling reaction of K[C6F5BF3] with 4-FC6H4I was studied. Based on the obtained results, a series of pentafluorobiphenyls C6F5C6H4X were prepared from K[C6F5BF3] and XC6H4I or 4-CF3C6H4Br in high yields under aerobic conditions.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
![The effect of N-heterocyclic carbene ligands in the palladium-catalyzed cross-coupling reaction of K[C6F5BF3] with aryl iodides and aryl bromides](/preview/png/5228947.png "First Page Preview: The effect of N-heterocyclic carbene ligands in the palladium-catalyzed cross-coupling reaction of K[C6F5BF3] with aryl iodides and aryl bromides")
Authors
Nicolay Yu. Adonin, Dmitrii E. Babushkin, Valentin N. Parmon, Vadim V. Bardin, Gennadiy A. Kostin, Vasiliy I. Mashukov, Hermann-Josef Frohn,