| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5229000 | Tetrahedron | 2005 | 8 Pages |
Abstract
Density functional computations were carried out with the objective of quantifying the interactions of bromine and chlorine atoms with neighboring cationic centers in a series of 1-aryl-2-haloethyl cations. Analyses of structural changes and bonding interactions between the positive center and the halogen gave rise to linear correlations with Ï+ values. Electron-donating groups diminished bridging and electron-withdrawing groups enhanced bridging.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Howard Haubenstock, Ronald R. Sauers,