Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5229146 | Tetrahedron | 2007 | 7 Pages |
Abstract
The insecticidal tetrahydroisocoumarin, (3R,4S,4aR)-4,8-dihydroxy-3-methyl-3,4,4a,5-tetrahydro-1H-2-benzopyran-1-one, was synthesized as a racemate and as an optically active form using one-pot esterification-Michael addition-aldol reaction of δ-hydroxy-α,β-unsaturated aldehyde and diketene as a key step.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Kanako Uchida, Ken Ishigami, Hidenori Watanabe, Takeshi Kitahara,