Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5229226 | Tetrahedron | 2007 | 9 Pages |
Abstract
Ireland-Claisen rearrangement, triggered by silyl enolization of allylic but-3-enoates 2, was achieved using DBU as the base in the presence of an excess amount of TMSCl to provide 2-ethylidene-γ,δ-unsaturated carboxylic acids 5 in good yields.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yunxia Li, Andreas Goeke, Ruiyao Wang, Quanrui Wang, Georg Fráter,