Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5229908 | Tetrahedron | 2005 | 7 Pages |
Abstract
The total synthesis of (3Z,6Z,9S,10R)-9,10-epoxy-1,3,6-heneicosatriene, sex pheromone component of Hyphantria cunea, using a convergent synthetic strategy, was achieved through the regioselective coupling of the two fragments, chiral epoxy tosylate and 1,4-diyne. The former fragment was synthesized in two efficient and convenient approaches starting from the same available material using Sharpless AE kinetic resolution as the key step.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Chao Che, Zhong-Ning Zhang,