Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5230438 | Tetrahedron | 2007 | 8 Pages |
Abstract
The synthesis and full characterization of new chromophores with second-order nonlinearities containing thienylpyrrolyl and benzothiazolyl moieties are reported. The solvatochromic behavior of the compounds was investigated. The hyperpolarizabilities β of derivatives 4-6 were measured using hyper-Rayleigh scattering and thermogravimetric analysis (TGA) was used to evaluate their thermal stability. The experimental results indicate that strong nonlinearity is balanced by good thermal stability especially for chromophores 6b and 6c, making them good candidates for NLO applications.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Rosa M.F. Batista, Susana P.G. Costa, Elisabeth L. Malheiro, Michael Belsley, M. Manuela M. Raposo,