| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5230709 | Tetrahedron | 2007 | 6 Pages |
Abstract
A new and an efficient synthesis of aryl alk-1-enyl sulfoxides is reported. The reaction between alane-pyridine complexes, triphenylphosphine, and sulfonyl chlorides affords the title products in good to excellent yields (70-94%) in short reaction times using mild conditions. The optimal ratio between reagents (alane-pyridine/PPh3/sulfonyl chloride 1.00/1.35/0.92) was obtained performing a chemiometric analysis. A rationale for the reaction was advanced.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
G. Signore, M. Calderisi, C. Malanga, R. Menicagli,