Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5230779 | Tetrahedron | 2007 | 9 Pages |
Abstract
Several 1- and 2-substituted thianthrene sulfilimine derivatives were prepared and the selectivity toward oxidation and N-tosylimination under several conditions was studied. In the photolysis of trans-5-(N-p-tosyl)iminothianthrene 10-oxide (trans-10), photo isomerization to cis-10 was observed. Further, photoimino-transfer reaction of sulfilimines and their 10-mono- and -dioxide derivatives to sulfides was intensively studied to make clear the ability as nitrene precursors.
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Chemistry
Organic Chemistry
Authors
Tomoyuki Fujita, Hideo Kamiyama, Yasushi Osawa, Hiroyuki Kawaguchi, Bung Ju Kim, Atsushi Tatami, Wataru Kawashima, Tetsuo Maeda, Atsushi Nakanishi, Hiroyuki Morita,