| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5231475 | Tetrahedron | 2005 | 39 Pages |
Abstract
The Nazarov cyclisation is revisited. Recent improvements such as metal-catalysed Nazarov cyclisation, asymmetric Nazarov cyclisation, cationic cyclopentannelation of allenyl ethers, fluorine-directed Nazarov cyclisation, trapping of the photochemically generated oxyallyl zwitterions, and procedures called 'interrupted Nazarov reactions' have widely expanded the synthetic scopes of the process.
Keywords
TBDPStrifluoroethanoltrimethylsilylTFSAPMBDIBCyclopentenoneHMTADPPEBF3·Et2Otert-butoxycarbonylCyclopentadienylTfOHFuraneTMSp-toluenesulphonic acidp-methoxybenzoylp-methoxyphenyltetrahydropyranyltriisopropylsilyltrifluoromethanesulphonic acidTsOHTFEPMPTHFCbzTMSOTfTMPTBDMSTFACyclohexylHFIPCHXBOCPPATHParylBoron trifluoride etherateethylTriflic acidTrifluoroacetic acidLewis acidPolyphosphoric acidElectrocyclisationbenzyloxycarbonylbutylEnantiomeric excessTetrahydrofurantert-butyldiphenylsilyltert-butyldimethylsilylphenylMethylTIPShexafluoro-2-propanolHexamethylenetetraminePropylPyridine
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Hélène Pellissier,