| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5231923 | Tetrahedron | 2005 | 15 Pages |
Abstract
ÎVi*=ÎV0*+ÎVÏ* (ÎV0*: activation volume of the unhindered reaction, ÎVÏ*: steric volume component) The paper reviews the recent progress made in the high-pressure relief of steric inhibition in congested reactions. The correlation between pressure and steric interactions is illustrated by comprehensive examples and rationalized via useful Hammond postulate. The report contains 96 references.
Related Topics
Physical Sciences and Engineering
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Authors
Gérard Jenner,