Article ID Journal Published Year Pages File Type
5233010 Tetrahedron 2005 8 Pages PDF
Abstract
The reaction of α-keto esters with cyclopent-2-enone catalyzed by tertiary-phosphine organocatalyst of diphenylmethylphosphine provides the corresponding Baylis-Hillman adducts in higher yields. While the similar reaction of α-keto esters with cyclopent-2-enone furnishes the corresponding aldol adducts in the presence of tertiary-amine organocatalyst of DBU.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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