Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5248459 | Tetrahedron | 2011 | 7 Pages |
Abstract
The acid mediated decomposition of the Diels-A1der adduct of 1,3-cyclopentanedione with anthracene was studied. An extremely facile, acid catalyzed retro-Diels-Alder fragmentation produces 2-methylene-1,3-cyclopentanedione, which undergoes twofold electrophilic substitution on the cognate anthracene nucleus.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
William H. Bunnelle, W. Randall Shangraw,