Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52491 | Catalysis Communications | 2007 | 5 Pages |
Abstract
Copper doped ceria and ceria–zirconia mixed oxides were synthesized using the citric acid sol–gel method. The temperature-programmed oxidation (TPO) results showed that the Cu modification improved the low-temperature activity and the selectivity to CO2 of ceria for soot oxidation in the presence of NO and excess oxygen even after ageing at 800 °C for 20 h in flow air. Meanwhile, not only the segregation of Cu and sintering of CuO, but also the separation of Ce- and Zr-rich phases worsened the activity of the Cu–Ce–Zr catalyst after the high-temperature calcination.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Xiaodong Wu, Qing Liang, Duan Weng, Zhenxiang Lu,