| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5251744 | Tetrahedron | 2011 | 11 Pages |
Abstract
A series of trans- and cis-2,3-di R)oxy-1,4-dIoxanes (R = Me,Ph, Ac) and some 2,5-disubstituted analogis were prepared and analysed by various NMR techniques. The trans isomers occur in more than 96% as diaxial conformers. Molecular mechanics calculations largely confirm these findings, which are interpreted -in terms of combined anomeric and gauche effects.
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Authors
Benzion Fuchs, Aviyakar Ellencweig, Ulrich Burkertâ ,