Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52566 | Catalysis Communications | 2007 | 6 Pages |
Abstract
Diphosphino-functionalized MCM-41 anchored palladium(0) complex (denoted as MCM-41-2P-Pd(0)) was conveniently synthesized from commercially available and cheap γ-aminopropyltriethoxysilane via immobilization on MCM-41, followed by reacting with diphenylphosphinomethanol and palladium chloride and then the reduction with hydrazine hydrate. XRD and XPS spectroscopies were employed to characterize the title palladium complex. It was found that this complex is a highly active and stereoselective catalyst for Heck arylation of conjugated alkenes with aryl halides and can be reused many times without loss of activity.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Mingzhong Cai, Junchao Sha,