Article ID Journal Published Year Pages File Type
5261220 Tetrahedron Letters 2014 4 Pages PDF
Abstract
Nucleophilic species of tellurium and sulfur were generated in situ from the reaction of the respective diorganyl dichalcogenides with NaBH4 in PEG-400 as solvent and selectively added to electron-deficient alkenes. Chalcogenolate anions were directly added at mild conditions by this simple procedure and in all cases furnished the respective Michael adducts in short reaction times and good yields.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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