Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5261229 | Tetrahedron Letters | 2014 | 4 Pages |
Abstract
Binuclear iron(III) octakis(perfluorophenyl)tetraazaporphyrin μ-oxodimer complex was prepared by the reaction of bis(perfluorophenyl)maleonitrile and Fe(CO)5 and tested in catalytic oxygenation reactions of several hydrocarbons in comparison with the analogous non-fluorinated phthalocyanine complexes. Results of the study demonstrate that this complex is a highly efficient catalyst for the oxygenation of anthracene, 2-tert-butylanthracene, naphthalene, 2-methylnaphthalene, phenanthrene, adamantane, and toluene using iodosylbenzene, oligomeric iodosylbenzene sulfate, or Oxone as stoichiometric oxidants.
Related Topics
Physical Sciences and Engineering
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Authors
Mekhman S. Yusubov, Cumali Celik, Margarita R. Geraskina, Akira Yoshimura, Viktor V. Zhdankin, Victor N. Nemykin,