Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52616 | Catalysis Communications | 2006 | 6 Pages |
Abstract
Effect of Pd loading to NiO–MgO solid solution was investigated on catalytic activity and inhibition of carbon deposition in oxidative steam reforming of methane. Under atmospheric pressure, Pd/Ni0.2Mg0.8O exhibited much higher methane conversion than Ni0.2Mg0.8O and Pd/MgO catalysts by the enhancement of reduction degree of Ni and the formation of Pd–Ni alloy. Under pressurized conditions, 0.1% Pd/Ni0.2Mg0.8O catalyst showed high and stable activity; and the amount of deposited carbon was negligible. In contrast, the deactivation was clearly observed over Ni0.2Mg0.8O, Pd/MgO and other Pd/Ni0.2Mg0.8O catalysts, and the deactivation rate was closely related to the amount of deposited carbon.
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Authors
Mohammad Nurunnabi, Shigeru Kado, Kimihito Suzuki, Ken-ichiro Fujimoto, Kimio Kunimori, Keiichi Tomishige,