| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5261618 | Tetrahedron Letters | 2014 | 5 Pages |
Abstract
We report the efficient synthesis of tetrabicycloporphyrin titanyl and vanadyl without decomposition of the bicyclo[2.2.2]octadiene unit. The complexes were heated under vacuum to give titanyl and vanadyl tetrabenzoporphyrins in 100% yield. We also titanylated and vanadylated tetra[2,3]naphthoporphyrin and tetra[2,3]anthraporphyrin, which have a greater degree of Ï conjugation than tetrabenzoporphyrin.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Satoshi Ito, Takahiro Ito, Daishi Makihata, Yutaro Ishii, Yuki Saito, Toru Oba,