| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 52634 | Catalysis Communications | 2006 | 5 Pages |
Abstract
A novel three-dimensional microporous ruthenium (II,III) polymer complex, [Ru2II,III(H2TCPP)]BF4 (1) (H2TCPP = 4,4′,4′,4‴-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis benzoic acid) was synthesized and characterized by elemental analysis, TG/DTA, magnetic susceptibility, FT-IR, diffuse reflectance UV–Vis, ESR, X-ray powder diffraction, BET analysis, and nitrogen and oxygen adsorption measurements. Complex 1 exhibited an effective catalytic performance for the heterogeneous oxidation of various types of alcohols, particularly primary aliphatic alcohols, with molecular oxygen and air without any additives at room temperature.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Chika Nozaki Kato, Masato Ono, Tomonari Hino, Tetsushi Ohmura, Wasuke Mori,