Article ID Journal Published Year Pages File Type
5263886 Tetrahedron Letters 2014 4 Pages PDF
Abstract
Three complementary strategies have been explored to obtain stereodefined 1,3 diols starting from easily accessible syn β-hydroxy acylsilanes: fluoride induced migrations of substituents on silicon, a Grignard addition followed by protodesilylation and Tischenko-type reactions. Preliminary data on scope and limitations of these processes are presented.
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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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