Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5263886 | Tetrahedron Letters | 2014 | 4 Pages |
Abstract
Three complementary strategies have been explored to obtain stereodefined 1,3 diols starting from easily accessible syn β-hydroxy acylsilanes: fluoride induced migrations of substituents on silicon, a Grignard addition followed by protodesilylation and Tischenko-type reactions. Preliminary data on scope and limitations of these processes are presented.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Gangireddy PavanKumar Reddy, Akondi Srirama Murthy, J. Satyanarayana Reddy, Saibal Das, Thierry Roisnel, Jhillu S. Yadav, Srivari Chandrasekhar, René Grée,