Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5264417 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
Hydantoin derivatives have been established as the observed product in the reaction of aryl isocyanates with dimethoxycarbene. A change in the reactivity profile of dimethoxycarbene with aryl isocyanates was observed upon the addition of a metal species. Methodology has been developed in which the outcome of nucleophilic carbene reactions with isocyanates can be controlled with simple changes to reaction conditions.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
James H. Rigby, Stephanie A. Brouet,