Article ID Journal Published Year Pages File Type
5264417 Tetrahedron Letters 2013 4 Pages PDF
Abstract
Hydantoin derivatives have been established as the observed product in the reaction of aryl isocyanates with dimethoxycarbene. A change in the reactivity profile of dimethoxycarbene with aryl isocyanates was observed upon the addition of a metal species. Methodology has been developed in which the outcome of nucleophilic carbene reactions with isocyanates can be controlled with simple changes to reaction conditions.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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