Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5264554 | Tetrahedron Letters | 2013 | 5 Pages |
Abstract
N-Ferrocene (Fc)/porphyrin (Por) [5,6]-open azafulleroids and [6,6]-closed aziridinofullerenes have been synthesized for the first time. Electrochemical measurements revealed that chromophores attached to [5,6]-open azafulleroids are more easily oxidizable than those attached to [6,6]-closed aziridinofullerenes. This was attributed to the delocalization degree of the nitrogen lone-electron pair involved in aziridinofullerene that is larger than that in azafulleroid.
Related Topics
Physical Sciences and Engineering
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Authors
Chen Chen, Yi-Zhou Zhu, Hai-Ying Zhao, Jian-Yu Zheng,