Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5265052 | Tetrahedron Letters | 2013 | 4 Pages |
Abstract
An aerobic, organocatalytic, and aqueous method for the oxidation of sulfides is described. Synthetic flavin, 5-ethyl-3,7,8,10-tetramethylisoalloxazinium perchlorate, acts as an efficient catalyst for the oxidation of sulfides in water under an oxygen atmosphere (1Â atm) with the assistance of ascorbic acid as a reductant. This is an inexpensive, convenient, and environmentally benign method for the selective oxidative transformation of sulfides into sulfoxides.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Yasushi Imada, Takahiro Kitagawa, Han-Kun Wang, Naruyoshi Komiya, Takeshi Naota,