Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5265495 | Tetrahedron Letters | 2012 | 5 Pages |
Abstract
Direct C-H arylation of unactivated heteroaromatics with aryl halides catalyzed by cobalt porphyrin is reported. The reaction is proposed to go through a homolytic aromatic substitution reaction. The aryl radical is electrophilic and a SOMO-HOMO interaction is predominant in the aryl radical addition process.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Ying Ying Qian, Ka Lai Wong, Meng Wen Zhang, Tsz Yiu Kwok, Ching Tat To, Kin Shing Chan,