| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5265598 | Tetrahedron Letters | 2012 | 6 Pages |
Abstract
We report a new in situ borylation method of aryl or vinyl halides and triflates using tetrakis(dimethylamino)diboron, DMA4B2, as a borylating agent in the presence of a diol. Reaction conditions and catalysts closely follow the Miyaura Pin2B2-borylation. A broad range of substrates, solvents and diols are suitable for this reaction making the in situ borylation protocol very attractive for borylation applications at commercial scale.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Charles S. Bello, Joachim Schmidt-Leithoff,