Article ID Journal Published Year Pages File Type
5266119 Tetrahedron Letters 2012 4 Pages PDF
Abstract
Bis(tert-butylperoxy)iodobenzene, generated in situ by the reaction between diacetoxyl iodobenzene (DIB) and tert-butyl hydroperoxide (TBHP), was used in the oxidative transformation of primary azides to nitriles, and secondary azides to ketones.
Keywords
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Preview
Oxidative transformation of azides to aryl nitriles using DIB/TBHP: scope and mechanistic insights
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