Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
52665 | Catalysis Communications | 2007 | 5 Pages |
Abstract
An oxotungsten–silica mesoporous structure (WSBA-15) has a hierarchical crystalline architecture in which the W dopants possess tetrahedral coordination geometries for the mixed-valence states W6+, W5+, and W4+. The WSBA-15 catalyst can be recycled—without any loss of activity—for the direct oxidation (30% H2O2) of cyclohexene to colorless, crystalline adipic acid (55% yield) under organic solvent-free conditions.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Catalysis
Authors
Ching-Yuan Cheng, Kuan-Jiuh Lin, Muppa R. Prasad, Shu-Juan Fu, Sheng-Yueh Chang, Shin-Guang Shyu, Hwo-Shuen Sheu, Chia-Hao Chen, Cheng-Hao Chuang, Minn-Tsong Lin,