| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5266592 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
The crystal structures of tetrathiahemicarceplexes 1,4-diiodobenzene@1 and 4-iodotoluene@1 are reported. From the crystal structures and 1H NMR experiment the kinetic versus thermodynamic complexation shifts of 4-iodotoluene@1 were observed. The four thia groups of tetrathiahemicarceplex cooperatively built ‘the bottleneck’ leading to the equilibrium shift of carceroisomers.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slide
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
