Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5266746 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
Chiral tetrahydropentalenes catalyze the 1,4-addition of vinylboronic acids to cyclic enones in the presence of the Rh-complexes. The stereochemistry of the reaction was controlled by the steric properties of the aryl groups in the tetrahydropentalenes as well as by the substitution pattern of the boronic acids.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Sarah Helbig, Kirill V. Axenov, Stefan Tussetschläger, Wolfgang Frey, Sabine Laschat,