Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5267723 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
The addition of allyltitanium reagents, generated by the desulfurizative titanation of allylic sulfides with the titanocene(II) reagent Cp2Ti−1-butene, to α-chiral ketones produced tertiary homoallylic alcohols bearing three adjacent chiral centers with high diastereoselectivity.
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