Article ID Journal Published Year Pages File Type
5267723 Tetrahedron Letters 2012 4 Pages PDF
Abstract

The addition of allyltitanium reagents, generated by the desulfurizative titanation of allylic sulfides with the titanocene(II) reagent Cp2Ti−1-butene, to α-chiral ketones produced tertiary homoallylic alcohols bearing three adjacent chiral centers with high diastereoselectivity.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry