Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5267922 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
The catalytic enantioselective electrophilic chlorination promoted by chiral palladium complexes is described. The treatment of β-keto esters with 2,3,4,5,6,6-hexachlorocyclohex-2,4-dienone as chlorine source under mild reaction conditions afforded the corresponding α-chlorinated β-keto esters with excellent enantioselectivities (up to 94% ee).
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Young Ku Kang, Hee Hun Kim, Kwang Oh Koh, Dae Young Kim,