| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5268084 | Tetrahedron Letters | 2012 | 4 Pages |
Abstract
The copper(II) complex [Cu(C186tren)](Br)2, 2, is an efficient precatalyst for the Huisgen 'click' cycloaddtion which can be used at low loading without the requirement of an external sacrificial reductant such as sodium ascorbate. EPR studies support the in situ reduction of 2 by the alkyne to generate a reactive copper(I) catalyst.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Lydie Harmand, Marie-Hélène Lescure, Nicolas Candelon, Mathieu Duttine, Dominique Lastécouères, Jean-Marc Vincent,