Article ID Journal Published Year Pages File Type
5268304 Tetrahedron Letters 2015 4 Pages PDF
Abstract

Several new dicationic viologen sensitizers are synthesized and characterized both photo- and electro-chemically. Benzo-annulation of methyl viologen increases its fluorescence lifetime by a factor of 6.6. Similar lifetime increases were observed for methylated derivatives, that have the added advantage of enhanced solubilities. These electron transfer sensitizers can oxidize organic substrates with oxidation potentials of approximately 2.4 eV and lower.

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Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry