Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5268402 | Tetrahedron Letters | 2015 | 4 Pages |
This study focused on the aromatic plane effect of the binding modes between 'Texas-sized' molecular box and carboxylate anion species. The molecular box, namely cyclo[2](2,6-di(1H-imidazol-1-yl)pyridine)-[2](1,4-dimethylenebenzene) (14+; studied as the PF6â salt), easily constructs interpenetrated structures (i.e., pseudorotaxanes) with carboxylate anions via the introduction of aromatic rings. As revealed by 1H NMR titration, two-dimensional nuclear Overhauser effect spectroscopy (NOESY), UV-Vis spectroscopic study, and electrospray ionization mass spectrometry (ESI-MS), the determination effect of aromatic plane in the binding modes between 14+ and carboxylate anions was studied in detail. This research reveals the important role of aromatic plane substitute groups on anions for building anion-induced interpenetrated self-assembly structures.
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