| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5268439 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
The titanocene(II)-promoted reaction of α-(benzyldimethylsilyl)allylic sulfides with ketones proceeded with high regio- and stereoselectivity to give δ-silylhomoallylic alcohols. The following palladium catalyzed cross-couplings with organic halides produced anti-(E)-β,δ-disubstituted tertiary homoallylic alcohols with complete retention of configuration.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Takeshi Takeda, Hideki Wasa, Akira Tsubouchi,