| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5268637 | Tetrahedron Letters | 2010 | 6 Pages |
Abstract
Oxalyl chloride has been demonstrated to function as C1 carbonyl synthon in the carbonylations of triarylbismuth and triarylindium nucleophiles under palladium-catalyzed conditions. All the three aryl groups from both bismuth and indium reagents participated in carbonylative couplings to afford the corresponding functionalized ketones in high yields. This study also disclosed a novel utilization of oxalyl chloride as facile alternative source of CO for carbonylations under palladium catalysis.
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Authors
Maddali L.N. Rao, Varadhachari Venkatesh, Priyabrata Dasgupta,