| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5268877 | Tetrahedron Letters | 2011 | 4 Pages |
Abstract
Although Ito-Saegusa oxidation gives defined α,β-unsaturated ketones from silyl enol ether of ketones controlled by the position of the sp2 carbon of the silyl enol ether, the formation of a regioisomeric product that was oxidized abnormally was observed. The structural requirements for the substrates, the conditions, and a plausible mechanism are presented.
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Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Shiharu Hiraoka, Shinji Harada, Atsushi Nishida,