Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5269067 | Tetrahedron Letters | 2014 | 4 Pages |
Abstract
We present the first results of the intramolecular cyclization of propargyl ureas catalyzed by TBAF. Depending on the substituents close to the triple bond, imidazolone or methylene-imidazolidinone was obtained. The dual activation of the triple bond by interaction with TBAF via the cation-Ï is thought to be responsible.
Graphical abstractDownload high-res image (32KB)Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Florent Huguenot, Clémence Delalande, Michel Vidal,