Article ID Journal Published Year Pages File Type
5269121 Tetrahedron Letters 2011 5 Pages PDF
Abstract
The β-glycosyl esters of cis-cinnamic acid were synthesized directly using Hannesian's unprotected glycosyl donor and the carboxylic acid in toluene. This protocol does not require protecting groups on the glycosyl donors, and high stereoselectivity was achieved. The first synthesis of a potent allelochemical, 1-O-cis-cinnamoyl-β-d-glucopyranose, is also described.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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