| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5269131 | Tetrahedron Letters | 2011 | 5 Pages |
Abstract
The utility of arenediazonium salts immobilized in imidazolium-ILs [BMIMPF6 and BMIMBF4] for facile, high yielding, synthesis of olefins via the Pd(OAc)2-catalyzed Matsuda-Heck arylation reaction has been demonstrated. The reaction can also be performed as a two-step process in the IL starting from ArNH2, by sequential in-situ diazotization-arylation. Simple product isolation and the recycling/re-use of the IL are additional advantages of this one-pot method.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Rajesh G. Kalkhambkar, Kenneth K. Laali,