| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5270021 | Tetrahedron Letters | 2014 | 4 Pages |
Abstract
Conditions milder than those previously reported are shown to be generally applicable to the Pt-catalyzed insertion of non-carbonyl-stabilized diazoalkanes into B2pin2. Selective transformation of one (pinacolato)boryl unit in the products is enabled by rapid, low-temperature deboronation in the presence of a Lewis base and genesis of a highly reactive B-stabilized carbanion.
Keywords
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Andrew J. Wommack, Jason S. Kingsbury,