Article ID Journal Published Year Pages File Type
5270118 Tetrahedron Letters 2010 4 Pages PDF
Abstract

γ,δ-Unsaturated O-methyl oximes were cyclized to dihydropyrrole by the treatment of (1-butene)ZrCp23 prepared by Negishi's procedure (reaction with Cp2ZrCl2 and two equivalents of n-BuLi). In this cyclization, the geometry of oximes was affected and syn-oximes were cyclized efficiently. However, it was found that the anti-oxime is not suitable for the cyclization.

Graphical abstractDownload full-size image

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
Authors
, , , ,