Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5270158 | Tetrahedron Letters | 2010 | 4 Pages |
Abstract
(S)-4-Methyl-3,6-dihydro-2H-pyran-2-carbaldehyde (3), the common intermediate in the syntheses of the C17-C27 subunit of laulimalide (4) and (+)-faranal (5), the trail pheromone of the pharaoh ant, Monomorium pharaonis, were obtained via transformation of methyl 3-bromomethyl-3-butenoate (1) into allylstannane 2 and subsequent allylation of (benzyloxy)acetaldehyde (6) in accordance with the Keck procedure as the key steps.
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Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Iryna V. Mineyeva, Oleg G. Kulinkovich,