| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 5270231 | Tetrahedron Letters | 2010 | 4 Pages |
Abstract
Carbocyclic aminonucleosides and epi-4â²-carbocyclic puromycin were prepared from an acylnitroso-derived hetero Diels-Alder cycloadduct. Pd(0)/InI-mediated allylations of a formyl species were used to install the 4â²-hydroxymethyl group. A tethered aminohydroxylation strategy was employed to install the cis-2â²,3â²-aminoalcohol moiety with complete regio- and diastereocontrol.
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Cara Cesario, Lawrence P. Jr., Marvin J. Miller,