Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5270616 | Tetrahedron Letters | 2010 | 4 Pages |
Abstract
In this work, we report the first practical application of high-valent oxo-complexes for the reduction of alkenes to the corresponding alkanes. The catalytic system Ph(Me)2SiH/ReIO2(PPh3)2 (5 mol %) proved to be very efficient for the reduction of mono- and disubstituted alkenes under solvent-free conditions.
Graphical abstractThe system silane/oxo-rhenium complexes proved to be very efficient for the reduction of mono- and disubstituted alkenes.Download full-size image
Related Topics
Physical Sciences and Engineering
Chemistry
Organic Chemistry
Authors
Rita G. de Noronha, Carlos C. Romão, Ana C. Fernandes,